2023 A Level H2 Chemistry Paper 1 Solutions - Questions 21 to 30

Question 21

2023p1 q21

Answer: A

Topic: Halogenoalkane

Explanation:

The carbon bonded to bromine in 3-bromo-3-methylhexane is chiral and tertiary. The product mixture of 2 isomeric alcohols indicate mechanism is via SN1 to form an equimolar mixture of 2 optical isomers ie racemic mixture.

Therefore only statement A is consistent with SN1 mechanism.

 2023p1 q21 explain

Question 22

2023p1 q22

Answer: B

Topic: Halogenoalkane

Explanation:

Comparing hydrolysis reaction, propanoyl chloride is most reactive since acid carbon is bonded to 2 electronegative elements hence acid carbon is most positive and attractive to nucleophiles.

Chlorobenzene is the least reactive as lone pair on Cl is delocalised into pi system of benzene hence C-Cl bond resonance stabilised and unreactive.

2023p1 q22 explain

Question 23

2023p1 q23

Answer: A

Topic: Alkene and Mole Concept

Explanation:

From the balanced equation for combustion of hydrocarbon CxHy, we can write out the mole ratio and volume ratio of CxHy, O2 and CO2.

By comparing mole ratio to volume ratio, we can solve for x = 5 and y = 10. Hence molecular formula for hydrocarbon is C5H10.

C5H10 can be cycloalkane such as unbranched cyclopentane or branched methylcyclobutane. It can also be alkene such as pent-1-ene or pent-2-ene. So all statements are correct.

2023p1 q23 explain

Question 24

2023p1 q24

Answer: B

Topic: Organic Chem Application

Explanation:

To deduce how heptane can be converted to methylbenzene, we have to draw a closed loop of 6 carbons with a methyl group attached to carbon-1.

Hence in order for the C8H18 isomer to form 1,4-dimethylbenzene, we have to draw a closed loop of 6 carbons with a methyl group attached to carbon-1 and another methyl group attached to carbon-4.

For each of these possible isomers we have to do a bit of trial and error to deduce that isomers 1 and 2 are correct.

2023p1 q24 explain

Question 25

2023p1 q25

Answer: D

Topic: Carboxylic Acid and Derivatives

Explanation:

The reaction is between acid chloride and phenol to form ester functional group. Hence ethanoyl chloride reacts with 4-methylphenol to form 4-methylphenylethanoate.

2023p1 q25 explain

Question 26

2023p1 q26

Answer: B

Topic: Carboxylic Acid and Derivatives

Explanation:

Functional groups such as carboxylic acids and phenols are more acidic than water and will dissociate in heavy water D2O to form HD2O+ and conjugate base. The reverse process is also possible where conjugate base accepts deuterium cation D+ from HD2O+ hence hydrogen is replaced by deuterium.

2023p1 q26 explain

Question 27

2023p1 q27

Answer: D

Topic: Nitrogen Compounds and Proteins

Explanation:

The repeat unit of primary structure of protein is -NHCHRCO- with positions:

1 - amine N
2 - carbon with R group
3 - acid C

Hence a tripeptide will also have the same repeat unit thrice.

Only structures 2 and 3 follow this repeat unit and are tripeptides.

2023p1 q27 explain

Question 28

2023p1 q28

Answer: A

Topic: Electrochemistry

Explanation:

Statement 1 is correct since only water is formed from hydrogen-oxygen fuel cell.

Statement 2 is correct.

Statement 3 is correct as hydrogen is oxidised to H+ hence electrons are released.

2023p1 q28 explain

Question 29

2023p1 q29

Answer: B

Topic: Electrochemistry

Explanation:

Statement 1 is correct. When standard hydrogen electrode is attached to a half-cell with negative E, SHE will have more positive E and undergoes reduction to form H2 gas.

Statement 2 is wrong since standard redox potential for SHE is 0.00V.

Statement 3 is wrong as 1.00 moldm-3 H2SO4 will give 2.00 moldm-3 H+ which is not standard conditions of 1.00 moldm-3.

2023p1 q29 explain

Question 30

2023p1 q30

Answer: C

Topic: Electrochemistry

Explanation:

From decrease in concentration of Cu2+ we can calculate moles of Cu2+ reduced and moles of electrons transferred.

Then we can use Faraday's equations to write an expression involving time t.

2023p1 q30 explain

Back to other 2023 A Level Paper 1 Questions

Found this Chemistry video useful?

This free chemistry video lesson is brought to you by Chemistry Guru, Singapore's leading JC Chemistry tuition centre since 2010.

Please like this video and share it with your friends!

Join my 18,000 subscribers on my YouTube Channel for new Chemistry videos every week.

Check out other A Level Chemistry Video Lessons here!

Need an experienced tutor to make Chemistry simpler for you?

Do consider signing up for my JC Chemistry Tuition classes at Bishan or on-demand video lessons!


Classes

Info

Resources

Videos