Determine Moles of Electrons Gained per Mole of Oxidising Agent

240110 question

Let's put down all the information we have from the question so far.

240110 info

96 dm3 of NO2 is oxidised to NO3- while 2 moles of XO4- is reduced.

These are the recommended 4 steps to determine oxidation state of unknown species from experimental data:

240110 4 steps

1. Determine moles of reactants

At room temperature and pressure, moles of NO2 = 96 / 24 = 4
Moles of XO4- = 2 (given)

2. Determine moles of electrons transferred in reaction

We need to balance the oxidation half equation of NO2 in acidic medium.

240110 oxidation half equation of NO2

From half equation, mole ratio of electron lost to NO2 is 1 to 1.

240110 mole ratio e to no2

Hence mol of electron lost by NO2 = mol of NO2 = 4 = mol of electron gained by XO4-

This step is fundamental since we know redox reaction is a total transfer of electrons from reducing agent to oxidising agent, so moles of electrons involved in oxidation of NO2 and reduction of XO4- will be the same.

3. Determine mole ratio of electrons to XO4-

240110 mole ratio e to xo4

This basically says that each XO4- gains 2 electrons, so the answer to this question will be B.

240110 answer

The question didn't require us to find final oxidation state of X, but we can easily do that since we know the initial oxidation state of X and change in oxidation state.

240110 reduction half equation of xo4

Initial OS of X in XO4- = +7
Change in OS = -2
Final OS of X in product = +7 - 2 = +5

Topic: Redox Titration, Physical Chemistry, A Level Chemistry, Singapore

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