How Changes in Pressure and Temperature affect POE

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221205 question

We want to deduce how increasing pressure and temperature affect the colour of an equilibrium mixture of NO2 and N2O4.

Let us first recap Le Chatelier's Principle learnt in Chemical Equilibria.

221205 LCP

Le Chatelier's Principle states that if a system in equilibrium is subjected to a change which disturbs the equilibrium, the system will respond to reduce, counteract or oppose the effect of the change partially.

For a more detailed discussion of how changes in concentration, pressure, temperature and adding catalyst affect the system, check out this video lesson.

Let's apply what we know to determine how this NO2 and N2O4 system will respond.

1. Increasing Pressure

221205 increase pressure

When pressure increases, position of equilibrium will shift right to favour the formation of less moles of gas in order to lower the pressure.

Concentration of brown NO2 will decrease and concentration of colourless N2O4 will increase.

Hence colour of the system will become lighter.

2. Increasing Temperature

221205 increase temp

When temperature increases, position of equilibrium will shift left to favour the endothermic reaction in order to absorb excess heat and lower temperature.

Concentration of brown NO2 will increase and concentration of colourless N2O4 will decrease.

Hence colour of the system will become darker.

Therefore the answer to this question will be option C.

221205 answer

Topic: Chemical Equilibria, Physical Chemistry, A Level Chemistry, Singapore

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